Change the default Calendar folder

When I switch to the Calendar Navigation (CTRL+2), I see multiple Calendars listed for the various accounts that I have.

However, new meeting requests which I receive do not always get added to the Calendar of that account.

For instance, meeting requests I receive for my personal POP3 account get added the Calendar folder of my Exchange account from work.

How can I set the default Calendar to be the one of my POP3 Calendar?